The elastic properties of single-crystal fayalite as determined by dynamical measurement techniques     

Donald G. Isaak  Earl K. Graham  Jay D. Bass  Hong Wang 《Pure and Applied Geophysics》1993,141(2-4):393-414

We present new elasticity measurements on single-crystal fayalite and combine our results with other data from resonance, pulse superposition interferometry, and Brillouin scattering to provide a set of recommended values for the adiabatic elastic moduliC _ij and their temperature variations. We use a resonance method (RPR) with specimens that were previously investigated by pulse superposition experiments. The nineC _ij of fayalite are determined from three new sets of measurements. One set of our newC _ij data is over the range 300–500 K. We believe that the relatively large discrep ncies found in someC _ij are due in large part to specimen inhomogeneities (chemical and microstructural) coupled with differences in the way various techniques sample, rather than only systematic errors associated with experimental procedures or in the preparations of the specimens.Our recommendeaC _ij's (GPa) and (C _ij/T) _p (GPa/K) are: The resulting values for the isotropic bulk and shear moduli,K _s and , and their temperature derivatives are:K _s=134(4) GPa; =50.7(0.3) GPa; (K _s/T) _p =–0.024(0.005) GPa/K; and (/T) _p =–0.013(0.001) GPa/K. An important conclusion is thatK _s increases as the Fe/(Fe+Mg) ratio in olivine is increased.  相似文献   

橄榄石的后尖晶石相变研究进展     

翟双猛  夏斌  陈汉林 《地球学报》2006,27(1):75-79

橄榄石在高温高压条件下分解为钙钛矿和方镁石(后尖晶石相变),这是地幔中最为重要的相变之一,被认为是660KM地震波速间断面的成因。现今所取得的重要进展表现在3个方面:①MG_2SI O_4的后尖晶石相变的原位X射线高温高压实验研究;②水、AL_2O_3以及压力标尺对后尖晶石相变的影响效应;③下地幔条件下地幔岩组分中的后尖晶石相变。在对研究进展进行概述的基础上,对目前存在的问题进行了分析并提出未来可能的研究方向。  相似文献   

南极三块（L3）陨石球粒结构类型及其矿物学物征     

陶克捷琚宜太  刘小汉李金雁 《岩石学报》2005,21(3):1015-1028

我国第16次南极考察队回收到6块稀少种类陨石-L3型,GRV99001,GRV99019,GRV99020,GRV99021, GRV99022,GRV99026。本文对其中3块陨石进行研究,研究它们的球粒结构和矿物化学成分．它们虽然都属于非平衡普通球粒陨石(L3),但它们的亚类不同,GRV 99001为L3．4,GRV99026为L3．5,GRV99019为L3．6．它们的球粒结构和球粒内的矿物晶体完整性和矿物组合变化比较大,橄榄石和辉石以高镁为特征．这三块陨石的球粒结构种类比较多,有班状的、炉条状的、扇形的和隐晶质的等．在GRV99001陨石中班状结构的球粒内能见到一个或两个以上完整的单晶橄榄石构成的球粒,也能见到多个细小的或是破碎橄榄石,被包裹在辉石晶体内．而在GRV99019和GRV99026陨石中只能见到多个细小单晶体或是破碎的橄榄石晶体．GRV99001陨石的炉条状结构,好象是由一条带状长石矿物,穿插在单个橄榄石晶体中构成．扇形和伞形结构的球粒,以一个点为中心,向外放射呈扇形．如GRV99019陨石中扇形结构球粒,它们是以辉石为主,陨硫铁充填在低钙辉石缝隙中,形成扇形．另一种是以多个点为中心,如GRV99001陨石,它们是由橄榄石、低钙辉石和长石质的玻璃,构成多个小伞形,形状类似三维立体的球,裂缝中也充填有金属矿物．隐晶质的球粒在GRV99026陨石中有两种,一种是在一厘米等于 100un时呈现隐晶质矿物,而放大到一厘米等于5un时,就可以清楚看到两种低钙辉石矿物,在低钙辉石中还有金属矿物．另一种隐晶质结构球粒由极细小破碎的橄榄石和辉石矿物构成．这三块陨石中的橄榄石和辉石都以高镁为特征．班状结构球粒,在GRV99001陨石中橄榄石的MgO-33．37-51．21,辉石为35．9-36．61;GRV99019陨石中橄榄石23．33-56．58,辉石 21．38-33．07;GRV99026陨石中橄榄石45．91-52．63,辉石34．48-37．35．扇形结构球粒,在GRV99001陨石中橄榄石29．94 -46．22,辉石28．17-30．36;GRV99019陨石中橄榄石29．17-34．38,辉石23．11-27．79．炉条状结构的球粒,在GRV99001 陨石中橄榄石51．84-56．03．隐晶质结构球粒,在GRV99026陨石中辉石20．17-21．54,橄榄石30．84-32．66．由此看出矿物晶体完整性越好镁的含量越高．  相似文献   

青藏高原北羌塘半岛湖新生代粗面玄武岩橄榄石电子探针和激光探针分析   总被引：4，自引：0，他引：4  

赖绍聪  伊海生  刘池阳  O'Reilly S Y 《矿物学报》2002,22(2):107-112

利用电子探针和激光探针剥蚀系统（LA-ICP-MS），对北羌塘新第三纪粗面玄武岩中的橄榄石主元素和微量、稀土元素进行了系统分析。结果表明，本区橄榄石Fo平均为88，属贵橄榄石种属。相对富集Ni、Co和重稀土，而强烈亏损轻稀土及Rb、Sr、Ba、Zr等大离子亲石元素。其稀土元素配分型配分型式与粗面玄武岩全岩稀土配分型式呈互补状态。  相似文献   

小松山超基性杂岩体橄榄石的岩组分析     

赵东宏 《陕西地质》2003,21(2):45-48

沿贺兰山台褶带北部西缘深大断裂带分布的小松山超基性杂岩体属岩浆结晶分异形成的似层状含铬岩体，岩组分析表明岩体中橄榄石具有高度的定向性。笔者通过研究认为，这种定向性系岩浆上侵过程中的流动分异作用影响造成，反映了小松山岩体系构造动荡环境下的产物。  相似文献   

Inclusions in diamonds from the K14 and K10 kimberlites, Buffalo Hills, Alberta, Canada: diamond growth in a plume?     

Rondi M. Davies  William L. Griffin  Suzanne Y. O''Reilly  Tom E. McCandless 《Lithos》2004,77(1-4):99-111

Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle).

Eclogitic diamonds have a broad range of C-isotopic composition (δ¹³C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ¹³C=−4.9‰ av.), except for two ¹³C-depleted peridotitic (δ¹³C=−11.8‰, −14.6‰) and one ¹³C-depleted websteritic diamond (δ¹³C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N).

The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface.  相似文献   

青海东昆仑东段加当橄榄辉长岩锆石U-Pb年代学、地球化学及地质意义     

孔会磊  李金超  栗亚芝  贾群子  国显正  张斌 《地质学报》2018,92(5):964-978

东昆仑古特提斯域镁铁—超镁铁质岩石的研究极为薄弱,对青海东昆仑东段加当橄榄辉长岩进行岩相学、年代学和地球化学分析,以期为东昆仑晚古生代—早中生代构造岩浆演化提供新的约束。利用LA-ICPMS锆石U-Pb定年技术,获得橄榄辉长岩加权平均年龄为249.7±3.0Ma(n=21,MSWD=0.105),表明岩体形成时代为早三叠世。岩石地球化学研究表明,加当橄榄辉长岩具有高Al_2O_3(14.71%~18.60%)、低TiO_2(0.07%~0.19%)、贫P2O5(0.02%)、低碱(K_2O+Na_2O=1.65%~2.01%)及Na_2OK_2O的特征,属亚碱性辉长岩。岩石微量元素总体上富集大离子亲石元素(LILE:Rb、Sr、Ba、Th、K)和Pb,相对亏损高场强元素(HFSE:Nb、Ta、P、Zr、Ti),稀土元素总量较低,ΣREE=9.79×10~(-6)~12.55×10~(-6),(La/Yb)N为5.61~28.51,平均11.43,显示轻稀土富集的特征,δEu=1.64~2.48,具有明显的Eu正异常。根据地球化学特征和微量元素判别图解,橄榄辉长岩源区为被俯冲改造的岩石圈幔源岩浆,岩浆在演化过程中遭受了上地壳物质的同化混染,并经历了一定程度的结晶分异作用。结合东昆仑区域构造演化,认为加当橄榄辉长岩是早三叠世阿尼玛卿古特提斯洋北向俯冲阶段岩浆活动的产物。  相似文献   

Alpine olivine- and titanian clinohumite-bearing assemblages in the Erro-Tobbio peridotite (Voltri Massif, NW Italy)   总被引：3，自引：0，他引：3  

M. SCAMBELLURI  E. H. HOOGERDUIJN STRATING  G. B. PICCARDO  R. L. M. VISSERS  E. RAMPONE 《Journal of Metamorphic Geology》1991,9(1):79-91

The microstructures in the Erro-Tobbio peridotite indicate several stages of recrystallization of olivine + titanian clinohumite-bearing assemblages. The development of these assemblages is closely associated with serpentinite mylonites, in which they occur in shear bands and foliations and are inferred to have grown synkinematically, in veins, and as post-kinematic radial aggregates. In the peridotite wall-rock adjacent to these mylonites, the same assemblages have recrystallized statically at the expense of original olivine and pyroxenes, mesh-textured chrysolite and antigorite veins. In addition, the olivine-bearing assemblage occurs in widespread vein systems. The brittle deformation of the peridotite resulting in the development of these vein systems is closely related to ductile deformation of metagabbroic dykes in the peridotite. Although early metasomatism resulted in extensive rodingitization of the gabbros, some dykes show an eclogitic assemblage of Na-clinopyroxene + garnet + chloritoid + chlorite ± talc. These observations, the microstructures and the mineral chemistry all suggest that the assemblages in the ultramafic rocks and metagabbros developed during a prograde evolution towards high pressures (>13–16 kbar, 450–550° C), and during subsequent decompression. This metamorphic evolution is considered to be related to Late Cretaceous intraoceanic subduction in the Alps-Apennine system and closure of the Piedmont-Ligurian basin.  相似文献   

含硫化物镁铁质-超镁铁质侵入体中橄榄石Mg、Ni含量的制约:原理、模式及Voisey's Bay侵入体样品研究(英文)   总被引：4，自引：0，他引：4  

李楚思  Edward M.Ripley 《地学前缘》2007,14(5):177-185

镁铁质-超镁铁质岩浆结晶分离早期形成镁铁矿物,镁铁矿物中的Ni和Mg是相容元素。随着结晶分离作用的进行,Ni、Mg在硅酸盐岩浆及后形成的硅酸盐物质中的丰度下降。橄榄石中Ni含量及硅酸盐物质MgO/FeO比值都与母岩浆的相关值相关,据此可推断母岩浆的信息,它们之间可由实验测得的系数相联系。当岩浆饱和硫化物时,在结晶分离过程中硫化物珠滴会与镁铁硅酸盐物质一道析出,同时,与硫化物非饱和岩浆相比,过多的Ni会随之析出。这也反映在Ni、Mg含量比无硫化物分离时有更迅速的降低上。Ni、Mg含量变化值可以在VoiseysBay侵入体的模式曲线上反映出,加拿大Labrador的这一侵入体赋存了一个世界级的Ni-Cu-Co硫化物矿床。过去的作法是将侵入体中橄榄石的Ni、Mg含量与Simkin和Smith得出的各种火成岩中橄榄石的Ni、Mg含量相比较以确定Ni亏损,进而假定橄榄石来自硫化物饱和、有经济价值的岩浆。现在的研究显示这种简单的对比会导致错误。将样品数据与模式曲线对比并反映出侵入体矿物结晶堆积特征是重要的方法。使用这一方法,样品数据能很好地被模式曲线拟合。以在VoiseysBay的研究为例,当硫化物液相与硅酸盐矿物被去除后,硫化物非饱和的分离作用期就会显现出来,随后是硅酸盐结晶作用期。  相似文献   

金刚石伴生矿物中的烃类包裹体问题(英文)     

F.I.KASSIMOVA F.P.MELNIKOV 《地学前缘》2001,8(3):53-56

首次在Mir金伯利岩筒中的锆石中发现了烃类包裹体。利用低温荧光光谱仪测定出烃类包裹体的成分为萘和菲的同系物 ,芘 ,1,12苯并芘等 ;其成分与Udachnaya岩筒中的橄榄石内的烃类和Mir岩筒中的石榴石中的烃类的成分相近。测定出锆石的δ13C值为 - 2 1 83‰～ - 3 3 5 4‰ ,与用榴辉岩共生组合中最轻的金刚石测出的同位素δ13C值范围相符。文中引述了有关有机物来源的讨论及多环芳烃 (PAH)由缩聚作用形成的论述。伴生矿物中相当数量的PAH的存在证明在形成金刚石及其伴生矿物的情况下 ,若有相当浓度的自由氢存在则可能发生缩聚作用。这些缩聚作用中碳的来源显然与形成金刚石时碳的来源是相同的 (即液态的CH4,CO及CO2 )。  相似文献